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Summary of Consonant + y + Vowel Syllables
キャ kya キュ kyu キョ kyo
シャ sya シュ syu ショ syo
チャ tya チュ tyu チョ tyo
ニャ nya ニュ nyu ニョ nyo
ヒャ hya ヒュ hyu ヒョ hyo
ミャ mya ミュ myu ミョ myo
リャ rya リュ ryu リョ ryo
ギャ gya ギュ gyu ギョ gyo
ジャ zya ジュ zyu ジョ zyo
ビャ bya ピャ pya ビュ byu ピュ pyu ビョ byo ピョ pyo
キャ occurs frequently as a representation of the initial consonant + vowel of English 'cab', alternating with カ ka. ギャ oocurs frequently as a representation of the initial consonant + vowel of English 'gab', alternating with ガ ga. Sy combinations (シャ、シュ、ショ) regularly correspond to the initial consonant of English 'show'. Like z before i, zy (ジャ、ジュ、ジョ) may correspond to the medial consonant of English 'ledger' or of 'measure'. Ty combinations (チャ、チュ、チョ) regularly correspond to the initial consonant of English 'chin'.
"...one-fourth of all the characters used in modern Japanese occur in three-fourths of all the most frequently occurring words. This means that by concentrating on learning approximately 500 select characters, the student is assured of being able to read 75% of all the high-frequency words he will encounter in modern literature." - The Kanji Way to Japanese Language Power.